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Rare Earth content and extraction

Our research has uncovered that while REEs are prevalent in AMD, their concentrations are relatively low, posing significant extraction challenges. Utilizing advanced ion exchange technology provided by our partner, Cwenga, we've been able to refine the extraction process for these valuable elements.

Image A2V testwork: left, the deep red colour AMD from a coal Mine dump in Mpumalanga, South Africa. Photo credit: Tamlyn Sasha Naidu; centre, Ion exchange resin conditioning before testing. Photo Credit: Nkosilomusa Moyo; and right, column testing ion exchange resin with AMD. Photo credit: Cwenga.
Ion Exchange Technology Explained

Ion exchange technology involves using charged resin materials to capture and “swap” specific ions from a solution, enabling the targeted removal or recovery of desired substances. In our initial phase, many different resins were tested, and it was found that REEs could be extracted from the AMD effectively using cationic exchange resins. However, the high levels of iron (Fe) in AMD present a challenge, as Fe can interfere with the REE ion exchange process. To enhance REE recovery, we are pursuing strategies either to remove the iron or prevent it from binding to the resins.

Images of different types and size ranges of ion exchange resin. Picture Credit: Cwenga
 

During this project, our team also identified other Critical Raw Materials (CRMs) in AMD. This discovery broadened our focus, realizing that AMD could be a source not just for REEs but for any CRM (based on economic viability and geographical distribution). Interestingly, these CRMs can migrate from water to the surrounding soil, which has led us to investigate phytoremediation as a potential recovery strategy.

Ongoing Research and Innovations

Our research is actively exploring ways to optimize iron removal before CRM extraction, improve the selectivity of separating individual REEs, and use organic acids to elute REEs from the IX resins effectively. In the meantime, check out our links below to delve deeper into our findings, or visit our engagement and dissemination page, for a full list of outputs.

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